I'm gonna cheat a little with this because the songs I'm applying to certain characters in shows I've watched are actually used in the show to describe the characters themselves.
The Leftovers- "Homeward Bound" for Kevin Garvey (some spoilers)
Fargo- "It's Hard To Be Humble" for Emmit Stussy
Song was used in an opening episode of season 3. The lyrics "Oh lord, it's hard to be humble/When you're perfect in every way" kinda sums up Emmit pretty well. He's rich, handsome (sans Ewan McGregor's wig), runs his own successful company, has a nice family, lives in a nice mansion- his life seems pretty perfect.